Stick spectra

LTE/Non-LTE: Choose LTE or Non-LTE.
If you choose LTE, please ignore # Calculate non-LTE # section.
If you choose Non-LTE, more details can be found from Non-LTE.

WnWlUnit: Choose to provide the range of wavenumber wn in unit of cm-1 (cm⁻¹), or wavelength in unit of um (μm) or nm.

Range: Give two values as the minimum and maximum of the wavenumber range in unit of cm⁻¹ or wavelength range in unit of μm or nm. Please use the same unit as WnWlUnit. Don’t use , or ; between these two numbers, just leave blank here.

Absorption/Emission: Choose Absorption or Emission.

The LTE intensity equation is:

\[ I(f \gets i) = \frac{g'{A}_{fi}}{8 \pi c \tilde{v}^2_{fi}} \frac{e^{-c_2 \tilde{E}'' / T} (1 - e^{-c_2 \tilde{v}_{fi} / T })}{Q(T)}. \]

The LTE emissivity equation is:

\[ \varepsilon (i \gets f) = \frac{g'{A}_{fi}hc}{4 \pi}\frac{e^{-c_2 \tilde{E}'/T}}{Q(T)}. \]

Temperatures

Temperatures: Please provide temperatures in unit K.

Temperatures

T = ?

296

296 K

300,1000,3000,8000

300 K, 1000 K, 3000 K, 8000 K

1000:5000:1000

1000 K, 2000 K, 3000 K, 4000 K, 5000 K

300, 3000

1000: 3000: 500

[300,3000]

[300, 3000]

Filters

UncFilter(Y/N), Threshold(Y/N), and QNsFilter(Y/N) are filters, please see Filters.

Plot stick spectra

PlotStickSpectra(Y/N): If you need plot a figure of stick spectra (intensity or emisivity), please write Y after PlotStickSpectra(Y/N), otherwise, write N.

PlotStickSpectraMethod: Choose to plot y-axis in linear lin or logarithm log.

PlotStickSpectraWnWl: Choose to plot x-axis with wavenumber wn in unit of cm-1 (cm⁻¹), or wavelength wl in unit of um (μm) or nm.

Y-axisLimitStickSpectra: If you need set the lower limit of y-axis for plotting, please write after Y-axisLimitStickSpectra, otherwise, the default lower limit y-axis is 1e-30 (\(=10^{-30}\)) in unit of cm/molecule.

Example

Save wavenumber in unit of cm⁻¹ in the file and plot logarithm stick spectra in unit of cm/molecule and wavenumber in unit of cm⁻¹.

# Calculate stick spectra or cross sections #
LTE/Non-LTE                             LTE                       # 'LTE' or 'Non-LTE'
Temperatures                            300,3000                  # Temperatures in unit of K
WnWlUnit                                wn         cm-1           # Wavenumber (wn in unit of cm-1) or wavelength (wl in unit of um or nm)
Range                                   0          30000          # Same unit as WnWlUnit
Absorption/Emission                     Absorption                # 'Absorption' or 'Emission'
UncFilter(Y/N)                          Y          0.01           # If Y, default value 0.01 cm-1
Threshold(Y/N)                          Y          1e-30          # If Y, default value 1e-30 cm/molecule
QNsFilter(Y/N)                          N          +/-[]   e/f[]  ElecState[]  v[1,1;1,0;2,;,0]  


# Calculate stick spectra #
PlotStickSpectra(Y/N)                   Y          
PlotStickSpectraMethod                  log                       # Plot in linear (lin) or logarithm (log)
PlotStickSpectraWnWl                    wn         cm-1           # Wavenumber (wn in unit cm-1) or wavelength (wl in unit[nm or um])
Y-axisLimitStickSpectra                 1e-30                     # Default value is 1e-30 cm/molecule

Save wavenumber in unit of cm⁻¹ in the file and plot logarithm stick spectra in unit of cm/molecule and wavelength in unit of nm.

# Calculate stick spectra or cross sections #
LTE/Non-LTE                             LTE                       # 'LTE' or 'Non-LTE'
Temperatures                            1000:4000:1000            # Temperatures in unit of K
WnWlUnit                                wn         cm-1           # Wavenumber (wn in unit of cm-1) or wavelength (wl in unit of um or nm)
Range                                   0          30000          # Same unit as WnWlUnit
Absorption/Emission                     Absorption                # 'Absorption' or 'Emission'
UncFilter(Y/N)                          Y          0.01           # If Y, default value 0.01 cm-1
Threshold(Y/N)                          Y          1e-30          # If Y, default value 1e-30 cm/molecule
QNsFilter(Y/N)                          Y          +/-[]   e/f[]  ElecState[]  v[]  


# Calculate stick spectra #
PlotStickSpectra(Y/N)                   Y          
PlotStickSpectraMethod                  log                       # Plot in linear (lin) or logarithm (log)
PlotStickSpectraWnWl                    wl         nm             # Wavenumber (wn in unit cm-1) or wavelength (wl in unit[nm or um])
Y-axisLimitStickSpectra                 1e-30                     # Default value is 1e-30 cm/molecule

Save wavenumber in unit of μm in the file and plot linear stick spectra in unit of cm/molecule and wavelength in unit of nm.

# Calculate stick spectra or cross sections #
LTE/Non-LTE                             LTE                       # 'LTE' or 'Non-LTE'
Temperatures                            300                       # Temperatures in unit of K
WnWlUnit                                wl         um             # Wavenumber (wn in unit of cm-1) or wavelength (wl in unit of um or nm)
Range                                   0          30000          # Same unit as WnWlUnit
Absorption/Emission                     Absorption                # 'Absorption' or 'Emission'
UncFilter(Y/N)                          Y          0.01           # If Y, default value 0.01 cm-1
Threshold(Y/N)                          Y          1e-30          # If Y, default value 1e-30 cm/molecule
QNsFilter(Y/N)                          Y          +/-[]   e/f[]  ElecState[]  v[]  


# Calculate stick spectra #
PlotStickSpectra(Y/N)                   Y          
PlotStickSpectraMethod                  lin                       # Plot in linear (lin) or logarithm (log)
PlotStickSpectraWnWl                    wl         nm             # Wavenumber (wn in unit cm-1) or wavelength (wl in unit[nm or um])
Y-axisLimitStickSpectra                 1e-30                     # Default value is 1e-30 cm/molecule

Example

# Data source #
Database                                ExoMol
Molecule                                MgH
Isotopologue                            24Mg-1H
Dataset                                 XAB
SpeciesID                               666


# File path #
ReadPath                                /mnt/data/exomol/exomol3_data/
SavePath                                /home/jingxin/data/pyexocross/
LogFilePath                             /home/jingxin/data/pyexocross/log/MgH_ExoMol_stick_Ab.log


# Functions #
Conversion                              0
PartitionFunctions                      0
SpecificHeats                           0
CoolingFunctions                        0
Lifetimes                               0
OscillatorStrengths                     0
StickSpectra                            1
CrossSections                           0


# Cores and chunks #
NCPUtrans                               4
NCPUfiles                               1
ChunkSize                               1000000
RunMode                                 CPU                       # CPU(default) or GPU
GPUBackend                              AUTO                      # AUTO(default), CUDA, PyTorch-CUDA, CuPy-CUDA, or MPS (used only when RunMode=GPU)
GPUBatchLines                           8192                      # GPU line-batch size (only used when RunMode=GPU)
GPUBatchGrid                            256                       # GPU grid-batch size (only used when RunMode=GPU)


# Quantum numbers for conversion, stick spectra and cross sections #
QNslabel                                +/-  e/f   ElecState    v     Lambda   Sigma    Omega
QNsformat                               %1s  %1s   %12s         %3d   %3d      %5.1f    %5.1f


# Calculate stick spectra or cross sections #
LTE/Non-LTE                             LTE                       # 'LTE' or 'Non-LTE'
Temperatures                            300,3000                  # Temperatures in unit of K
WnWlUnit                                wn         cm-1           # Wavenumber (wn in unit of cm-1) or wavelength (wl in unit of um or nm)
Range                                   0          30000          # Same unit as WnWlUnit
Absorption/Emission                     Absorption                # 'Absorption' or 'Emission'
UncFilter(Y/N)                          Y          0.01           # If Y, default value 0.01 cm-1
Threshold(Y/N)                          Y          1e-30          # If Y, default value 1e-30 cm/molecule
QNsFilter(Y/N)                          N          +/-[]   e/f[]  ElecState[]  v[1,1;1,0;2,;,0]  


# Calculate stick spectra #
PlotStickSpectra(Y/N)                   Y          
PlotStickSpectraMethod                  log                       # Plot in linear (lin) or logarithm (log)
PlotStickSpectraWnWl                    wn         cm-1           # Wavenumber (wn in unit cm-1) or wavelength (wl in unit[nm or um])
Y-axisLimitStickSpectra                 1e-30                     # Default value is 1e-30 cm/molecule
# Data source #
Database                                ExoMol
Molecule                                NO
Isotopologue                            14N-16O
Dataset                                 XABC
SpeciesID                               81


# File path #
ReadPath                                /mnt/data/exomol/exomol3_data/
SavePath                                /home/jingxin/data/pyexocross/
LogFilePath                             /home/jingxin/data/pyexocross/log/NO_HITRAN_stick_Em_T2000_wl150-1000.log


# Functions #
Conversion                              0
PartitionFunctions                      0
SpecificHeats                           0
CoolingFunctions                        0
Lifetimes                               0
OscillatorStrengths                     0
StickSpectra                            1
CrossSections                           0


# Cores and chunks #
NCPUtrans                               8
NCPUfiles                               1
ChunkSize                               1000000
RunMode                                 CPU                       # CPU(default) or GPU
GPUBackend                              AUTO                      # AUTO(default), CUDA, PyTorch-CUDA, CuPy-CUDA, or MPS (used only when RunMode=GPU)
GPUBatchLines                           8192                      # GPU line-batch size (only used when RunMode=GPU)
GPUBatchGrid                            256                       # GPU grid-batch size (only used when RunMode=GPU)


# Quantum numbers for conversion, stick spectra and cross sections #
QNslabel                                J       X     Omega   v1      Sym    F
QNsformat                               %5.1f   %2s   %3s     %2d     %1s    %5s


# Calculate stick spectra or cross sections #
LTE/Non-LTE                             LTE                       # 'LTE' or 'Non-LTE'
Temperatures                            2000:4000:500             # Temperatures in unit of K
WnWlUnit                                wl         nm             # Wavenumber (wn in unit of cm-1) or wavelength (wl in unit of um or nm)
Range                                   150        1000           # Same unit as WnWlUnit
Absorption/Emission                     Emission                  # 'Absorption' or 'Emission'
UncFilter(Y/N)                          Y          0.01           # If Y, default value 0.01 cm-1
Threshold(Y/N)                          Y          1e-30          # If Y, default value 1e-30 cm/molecule
QNsFilter(Y/N)                          Y          X[]       Omega[]       v1[1,0;2,]


# Calculate stick spectra #
PlotStickSpectra(Y/N)                   Y          
PlotStickSpectraMethod                  log                       # Plot in linear (lin) or logarithm (log)
PlotStickSpectraWnWl                    wn         cm-1           # Wavenumber (wn in unit cm-1) or wavelength (wl in unit[nm or um])
Y-axisLimitStickSpectra                 1e-30                     # Default value is 1e-30 cm/molecule
# Data source #
Database                                HITRAN
Molecule                                NO
Isotopologue                            14N-16O
Dataset                                 NO-HITRAN
SpeciesID                               81


# File path #
ReadPath                                /home/jingxin/data/HITRAN/
SavePath                                /home/jingxin/data/pyexocross/
LogFilePath                             /home/jingxin/data/pyexocross/log/NO_HITRAN_stick_Em_T1000_wn1000-5000.log


# Functions #
Conversion                              0
PartitionFunctions                      0
SpecificHeats                           0
CoolingFunctions                        0
Lifetimes                               0
OscillatorStrengths                     0
StickSpectra                            1
CrossSections                           0


# Cores and chunks #
NCPUtrans                               32
NCPUfiles                               1
ChunkSize                               1000000
RunMode                                 CPU                       # CPU(default) or GPU
GPUBackend                              AUTO                      # AUTO(default), CUDA, PyTorch-CUDA, CuPy-CUDA, or MPS (used only when RunMode=GPU)
GPUBatchLines                           8192                      # GPU line-batch size (only used when RunMode=GPU)
GPUBatchGrid                            256                       # GPU grid-batch size (only used when RunMode=GPU)


# Quantum numbers for conversion, stick spectra and cross sections #
QNslabel                                J       X     Omega   v1      Sym    F
QNsformat                               %5.1f   %2s   %3s     %2d     %1s    %5s


# Calculate stick spectra or cross sections #
LTE/Non-LTE                             LTE                       # 'LTE' or 'Non-LTE'
Temperatures                            1000                      # Temperatures in unit of K
WnWlUnit                                wn         cm-1           # Wavenumber (wn in unit of cm-1) or wavelength (wl in unit of um or nm)
Range                                   1000       5000           # Same unit as WnWlUnit
Absorption/Emission                     Emission                  # 'Absorption' or 'Emission'
UncFilter(Y/N)                          N          0.005          # If Y, default value 0.01 cm-1
Threshold(Y/N)                          N          1e-30          # If Y, default value 1e-30 cm/molecule
QNsFilter(Y/N)                          N          X[]       Omega[]       v1[1,0;2,]


# Calculate stick spectra #
PlotStickSpectra(Y/N)                   N          
PlotStickSpectraMethod                  log                       # Plot in linear (lin) or logarithm (log)
PlotStickSpectraWnWl                    wn         cm-1           # Wavenumber (wn in unit cm-1) or wavelength (wl in unit[nm or um])
Y-axisLimitStickSpectra                 1e-30                     # Default value is 1e-30 cm/molecule